收稿日期: 2021-06-30
修回日期: 2021-11-19
网络出版日期: 2022-06-17
基金资助
国家自然科学基金项目“动力扰动遇含夹塞体硐室散射引起的围岩动态应力集中与破裂规律”(12072376);中山大学中央高校基本科研业务费专项资金(2021qntd15)
Study on Proportion and Mechanical Properties of Geopolymer Concrete
Received date: 2021-06-30
Revised date: 2021-11-19
Online published: 2022-06-17
混凝土是巷道支护过程中的重要建筑材料,然而混凝土在巷道施工中常常出现质量问题,为了不影响正常生产,需要对其进行修补。地聚合物混凝土凝结时间快,早期强度高,界面结合能力强,耐高温性和抗冻性强,耐腐蚀性良好,具有用作修补材料的潜力。以粉煤灰和矿粉为原料,Na2SiO3溶液和NaOH为碱激发剂制备地聚合物胶砂,研究不同的碱激发剂模数(1.0、1.2、1.4)和掺量(10%、15%、20%)对不同龄期胶砂力学性能的影响。结果表明:当碱激发剂模数为1.2,碱掺量为15%时,胶砂强度达到最大值。设计正交试验,研究了不同水胶比(0.45、0.50、0.55)、粉煤灰掺量(30%、50%、70%)和砂率(30%、35%、40%)对不同龄期地聚合物混凝土的工作性能和力学性能的影响。结果表明:粉煤灰掺量对抗压强度影响最为显著,水胶比次之,而砂率对强度发展几乎没有影响。最优的配合比为水胶比为0.50,粉煤灰掺量为50%,砂率为35%。
丁琴 , 陶明 , 李响 . 地聚合物混凝土配比及力学性能研究[J]. 黄金科学技术, 2022 , 30(2) : 243 -253 . DOI: 10.11872/j.issn.1005-2518.2022.02.082
Concrete is an important building material in roadway support,but there are often quality problems in roadway construction,such as honeycomb surface,cracks,holes and large area damage,which need to be repaired in order not to affect the normal production.Geopolymer concrete has the characteristics of fast setting time,high early strength,strong interface bonding ability,low permeability,high temperature resistance,frost resistance,corrosion resistance,excellent durability and low energy consumption,low pollution and low cost in the preparation process,and has the potential to be used as concrete repair materials.At present,there is no consensus on the proportion design of geopolymer concrete.The fly ash and slag were activated using sodium silicate and sodium hydroxide as alkalin-activator solution for the preparation of geopolymer mortar.The effects of different alkali-activator modulus (1.0,1.2,1.4) and content (10%,15%,20%) on the mechanical properties of mortar at different ages (3 d,7 d,28 d) were studied.The results show that the modulus and content of alkali-activator have a significant effect on the mechanical properties of geopolymers.Too large or too small alkali-activator modulus and content are not conducive to the strength development of geopolymer mortar.When the ratio of fly ash to slag is 1∶1,the modulus of water glass is 1.2,the content of alkali is 15%,the flexural and compressive strength of geopolymer mortar reaches the best value.The 28 d flexural strength is 7.6 MPa,the 28 d compressive strength is 72.3 MPa.In order to further explore the mechanical properties of geopolymer concrete with different mix ratios,the orthogonal experiment with three factors and three levels was designed to study the effects of different water-binder ratio (0.45,0.50,0.55),fly ash content (30%,50%,70%) and sand ratio (30%,35%,40%) on the workability and mechanical properties of geopolymer concrete at different ages (7 d,28 d).Taking the compressive strength as the evaluation index,the results show that fly ash content has the most significant effect on compressive strength,followed by water-binder ratio,and sand ratio has almost no effect on strength development.The results of variance analysis of 7 d and 28 d show that the content of fly ash has a highly significant effect on the compressive strength of geopolymer concrete,the water-binder ratio has a significant effect on the compressive strength of geopolymer concrete,but the sand ratio has no significant effect on the compressive strength of geopolymer concrete.Considering the workability and mechanical properties of geopolymer concrete,combined with the results of microstructure analysis,geopolymer concrete with water-binder ratio of 0.50 and fly ash content of 50% is a promising rapid repair material.
null | Cao Xiangyang, Yang Jiansen,2020.Overview of cementing properties of geopolymer and geopolymer concrete[J].Bulletin of the Chinese Ceramic Society,38(7):9. |
null | Fan Feilin, Xu Jinyu, Li Weimin,et al,2008.Study on the basic properties of slag and fly ash based geopolymeric concrete[J].Concrete,(6):58-61. |
null | Ghafoor M T, Khan Q S, Qazi A U,et al,2020.Influence of alkaline activators on the mechanical properties of fly ash based geopolymer concrete cured at ambient temperature[J].Construction and Building Materials,273(4):121752. |
null | Hung C, Chang J,2013.The influence of mixture variables for the alkali-activated slag concrete on the properties of concrete[J].Journal of Marine Science and Technology-Taiwan,21(3):229-237. |
null | Kurda R, Brito J, Silvestre J D,2017.Influence of recycled aggregates and high contents of fly ash on concrete fresh properties[J].Cement and Concrete Composites,84:198-213. |
null | Lee W K W, van Deventer J S J,2002.The effect of ionic contaminants on the early-age properties of alkali-activated fly ash-based cements[J].Cement and Concrete Research,32(4):577-584. |
null | Liu Dejun, Zuo Jianping, Liu Haiyan,et al,2020.Development and present situation of support theory and technology in coal mine roadway in China[J].Journal of Mining Science and Technology,5(1):22-33. |
null | Luo Xinchun, Wang Chang’an,2015.Effect of calcia content on structure and properties of metakaolin/blast furnace slag-based geopolymers[J].Journal of the Chinese Ceramic Society,43(12):1800-1805. |
null | Nath P, Sarker P K,2014.Effect of GGBFS on setting,workability and early strength properties of fly ash geopolymer concrete cured in ambient condition[J].Construct Build Mater,66:163-171. |
null | Rafeet A, Vinai R, Soutsos M,et al,2017.Guidelines for mix proportioning of fly ash/GGBS based alkali activated concretes[J].Construction and Building Materials,147:130-142. |
null | Rao G M, Rao T D G,2018.A quantitative method of approach in designing the mix proportions of fly ash and GGBS-based geopolymer concrete[J].Australian Journal of Civil Engineering,16(1):53-63. |
null | Ren Jinyang,2016.Study on the Mechanical Properties of Fly Ash Geopolymer Concrete [D].Yinchuan:Ningxia University. |
null | Shan Renliang, Peng Yanghao, Kong Xiangsong,et al,2019.Research progress of coal roadway support technology at home and abroad[J].Chinese Journal of Rock Mechanics and Engineering,38(12):2377-2403. |
null | Song W L, Zhu Z D, Peng Y Y,et al,2019.Effect of steel slag on fresh,hardened and microstructural properties of high-calcium fly ash based geopolymers at standard curing condition[J].Construction and Building Materials,229:116933.. |
null | Verma M, Dev N,2021.Effect of ground granulated blast furnace slag and fly ash ratio and the curing conditions on the mechanical properties of geopolymer concrete[J].Structural Concrete,(1):1-15. |
null | Wang H L, Li H H, Yan F Y,2005.Synthesis and mechanical properties of metakaolinite-based geopolymer[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,268(1/2/3):1-6. |
null | Weng L, Sagoe-Crentsil K,2007.Dissolution processes,hydrolysis and condensation reactions during geopolymer synthesis:Part II.High Si/Al ratio systems[J].Journal of Materials Science,42:2997-3006. |
null | Yang T, Yao X, Zhang Z H,2014.Quantification of chloride diffusion in fly ash-slag-based geopolymers by X-ray fluorescence (XRF)[J].Construction and Building Materials,69:109-115. |
null | Yin Ming, Bai Hongtao, Zhou Lü,2014.Strength characteristic of fly ash based geopolymer concrete[J].Bulletin of the Chinese Ceramic Society,33(10):2723-2727. |
null | Zhang Chunguang,2009.Study on Mine High-Performance Polymer Modified Concrete[D].Jiaozuo:Henan Polytechnic University. |
null | Zhang Dingwen, Wang Anhui,2020.Review on property of geopolymer binder and its engineering application[J].Journal of Architecture and Civil Engineering,37(5):13-38. |
null | 曹向阳,杨建森,2020.地聚合物及其混凝土的胶凝性质概述[J].硅酸盐通报,38(7):9. |
null | 范飞林,许金余,李为民,等,2008.矿渣—粉煤灰基地质聚合物混凝土的基本性能研究[J].混凝土,(6):58-61. |
null | 刘德军,左建平,刘海雁,等,2020.我国煤矿巷道支护理论及技术的现状与发展趋势[J].矿业科学学报,5(1):22-33. |
null | 罗新春,汪长安,2015.钙含量对偏高岭土/矿渣基地聚合物结构和性能的影响[J].硅酸盐学报,43(12):1800-1805. |
null | 任进阳,2016.粉煤灰地聚物混凝土的力学性能研究[D].银川:宁夏大学. |
null | 单仁亮,彭杨皓,孔祥松,等,2019.国内外煤巷支护技术研究进展[J].岩石力学与工程学报,38(12):2377-2403. |
null | 尹明,白洪涛,周吕,2014.粉煤灰地质聚合物混凝土的强度特性[J].硅酸盐通报,33(10):2723-2727. |
null | 张春光,2009.矿用高性能聚合物改性混凝土研究[D].焦作:河南理工大学. |
null | 章定文,王安辉,2020.地聚合物胶凝材料性能及工程应用研究综述[J].建筑科学与工程学报,37(5):13-38. |
/
〈 | 〉 |