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黄金科学技术 >

2022 , Vol. 30 >Issue 2: 302 - 312

DOI: https://doi.org/10.11872/j.issn.1005-2518.2022.02.093

冶炼技术与装备研发

碳质金矿中碳质物及其“劫金”机理研究进展

  • 张辛未 , 1, 2 ,
  • 宋永辉 , 1 ,
  • 董萍 1 ,
  • 尹宁 1 ,
  • 廖龙 1 ,
  • 张盼盼 1
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  • 1. 西安建筑科技大学冶金工程学院，陕西省黄金与资源重点实验室，陕西 西安 710055
  • 2. 陕西国际商贸学院，陕西 西安 712046
宋永辉（1972-），男，陕西西安人，教授，从事低变质煤清洁转化、有色金属、贵金属冶金与资源综合利用技术开发及新材料制备研究工作。

张辛未（1991-），女，陕西咸阳人，博士研究生，从事金矿矿物加工和金矿资源综合回收利用等研究工作。

收稿日期: 2021-07-14

  修回日期: 2021-11-19

  网络出版日期: 2022-06-17

基金资助

国家自然科学基金项目“基于煤基电极的电吸附处理氰化废水技术及其应用基础研究”(51774227)

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Research Progress on Carbonaceous Matters and Its “Preg-robbing” Mechanism in Carbonaceous Gold Ores

  • Xinwei ZHANG , 1, 2 ,
  • Yonghui SONG , 1 ,
  • Ping DONG 1 ,
  • Ning YIN 1 ,
  • Long LIAO 1 ,
  • Panpan ZHANG 1
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  • 1. School of Metallurgical Engineering, Xi’an University of Architecture and Technology, Key Laboratory of Gold and Resources of Shaanxi Province, Xi’an 710055, Shaanxi, China
  • 2. Shaanxi Institute of International Trade & Commerce, Xi’an 712046, Shaanxi, China

Received date: 2021-07-14

  Revised date: 2021-11-19

  Online published: 2022-06-17

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本文亮点

碳质金矿是重要的难处理金矿资源之一，碳质物“劫金”是金浸出率低下的主要原因。碳质物组分复杂，不同组分的碳质物的“劫金”能力和“劫金”行为存在差异，磨矿和浸出环节对碳质物的“劫金”能力也会产生影响，这些因素均能直接影响金的浸出率。通过系统总结碳质金矿中碳质物在组成特征、“劫金”机理及“劫金”能力的影响因素等方面的研究进展，对碳质物“劫金”机理现有研究工作的不足及未来研究方向进行了探讨，为碳质金矿碳质物劫金机理及预处理工艺的研究提供了重要参考。

本文引用格式

张辛未 , 宋永辉 , 董萍 , 尹宁 , 廖龙 , 张盼盼 . 碳质金矿中碳质物及其“劫金”机理研究进展[J]. 黄金科学技术, 2022 , 30(2) : 302 -312 . DOI: 10.11872/j.issn.1005-2518.2022.02.093

Highlights

The carbonaceous matters in carbonaceous gold ores can adsorb the gold dissolved in the process of cyanide leaching，which seriously affects the recovery of gold and is one of the most important troubles in gold processing.Various pretreatment methods have been used to eliminate the harmful effects of carbonaceous matters in gold leaching processes.Due to the characteristics of carbonaceous matters such as fine particle size，wide distribution range of particle size，complex compositions and difficulty on separation，there are few achievements of in-depth research on carbonaceous matters in carbonaceous gold ores at home and abroad.The main research tends to the development and optimization of the pretreatment processes of carbonaceous gold ores.Some new discoveries have enriched the scientific understanding of carbonaceous matters.Many kinds of substances can absorb gold in leaching process，but in the presence of carbonaceous matters，the absorb ability of other substances is often ignored.Among these carbonaceous matters，organic carbon and elemental carbon with pore structure which is similar to activated carbon have strong “preg-robbing” ability.The compositions of organic carbon have not been determined so far，but the discovery of kerogen further sheds light on the compositions of organic carbon and the geological conditions under which it formed.The kerogen are an important gold-containing carrier in the form of porous powder and solid particles.The discovery of kerogen provides a new idea for the removal of organic carbon.The pore structure has been found to be a strong condition for carbonaceous matters to absorb gold.The conclusion that destroying the pore structure can reduce the “preg-robbing” ability of carbonaceous matters further proves the view that carbonaceous matters with pore structure can adsorb the dissolved gold.The complexation between humic acid and metal ions also provides a reference for the “preg-robbing” theory of organic carbon.Some studies have found that carbonaceous matters affect gold leaching process not only by the “preg-robbing” ability，but also due to the surface coating of gold by carbonaceous mattes in the grinding process，which seriously affects gold leaching.There are great differences in the ability of carbonaceous matters to absorb gold from different ores，which are mainly reflected in the different carbonaceous matters species，maturity grade and grinding fineness.These conclusions are of great significance to the study of carbonaceous matters.As a result，this paper summarizes and analyzes the classical theory and latest researches on the material composition，“preg-robbing” mechanism of carbonaceous matters and influence factors of “preg-robbing” ability in the carbonaceous gold ores，points out the research directions of “preg-robbing” mechanism，and provides an important reference for the selection of pretreatment technology of carbonaceous gold ores.

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脚注

http://www.goldsci.ac.cn/article/2022/1005-2518/1005-2518-2022-30-2-302.shtml

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