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Gold Science and Technology ›› 2014, Vol. 22 ›› Issue (1): 81-86.doi: 10.3969/j.issn.1005-2518.2014.01.081

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The Choice of Elements Determination Method for Regional Geochemical Survey Sample in Xinjiang Province

LIU Ling，ZHOU Yuanyang，GAO Fengli，MEN Qianni   

  1. No.5 Gold Geological Party of CAPF，Xi’an   710100，Shaanxi，China
  • Received:2013-08-30 Revised:2013-11-05 Online:2014-02-28 Published:2014-06-25

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Abstract:

It is the most important factor to ensure the quality of analytical data for analysis method of the regional geochemical survey samples.In this paper，11 mineral elements （V，Cr，Cu，Zn，Co，Ni，Ba，Ti，Mo，W，Pb） of the regional geological survey samples in a region of Xinjiang were jointly determined by Inductively Coupled Plasma Mass Spectrometry and X-ray Fluorescence Spectrometer.The results of same batch samples for ICP-MS and XRF were compared，and the best analysis method for different elements was optimized，the analytical method precision and accuracy were evaluated too.Finally，a set of scientific matching program was established which apply to analysis the regional geochemical survey samples.The detection limit and the precision of the method meet DZ0130.4-2006 and supplemental instructions for 1∶50 000 geochemical samples standards.The reliability of the method has been tested by elements determination in Standard Reference Materials and the results are in agreement with the certified values.The matching program（ICP-MS and XRF） is rapid and high sensitivity，and it can be used to geochemical mapping samples analysis.

Key words: ICP-MS, XRF, regional geological survey samples

CLC Number: 

  • O657

［1］ 李超岭，于庆文，张克信，等.数字区域地质调查基本理论与技术方法［M］.北京：地质出版社，2003.
［2］ 叶家瑜，江宝林.区域地球化学勘查样品分析方法［M］.北京：地质出版社，2004.
［3］ 王微.火焰原子吸收法连续测定土壤样品中的铜、铅、锌、钴、镍［J］.有色矿冶，2010，26（2）：57-59.
［4］ 刘淑亮，刘玖芬，张汝生.原子吸收法测定金矿中金的不确定度评定［J］.黄金科学技术，2013，21（2）：40-44.
［5］ 陶秋丽.酸溶—催化极谱法测定地质样品中的钨、钼［J］.陕西地质，2008，26（1）：82-86.
［6］ 李玉莲，敖迎春，孙宁，等.能量色散X射线荧光光谱仪快速测定土壤中Cu、Pb、Zn、Rb、Nb和Th 6种元素［J］.现代仪器，2012，18（6）：81-84.
［7］ 赵志强，杜晓冉，李铭，等.X荧光分析仪在地质工作中运用实例［J］.化工矿产地质，2005，27（1）：47-49.
［8］ 张庆建，丁仕丘，郭丘，等.黄金矿砂鉴别方法研究［J］.黄金科学技术，2013，21（4）：79-82.
［9］ 张凤霞，刘化峰，王岳，等.ICP-AES法测定金饰品中铜、铁、锌含量的不确定度评定［J］.黄金科学技术，2012，20（5）：67-70.
［10］ 裴彦.等离子体原子发射光谱法在金属矿石样品分析中的应用［J］.广州化工，2012，40（15）：41-42.
［11］ 郭振华，张立英.ICP-AES法测定地质样品中的主体元素［J］.化工矿产地质，2001，23（4）：249-251.
［12］ 周娅，杨定清，谢永红，等.ICP-AES法测定土壤中铬含量的不确定度评定［J］.四川环境，2012，31（2）：33-35.
［13］ 吴建政，黄权乾，严洁，等.锍试金—电感耦合等离子体质谱法测定勘查地球化学样品中超痕量的铂族元素［J］.黄金，2012， 33（6）：58-60.
［14］ 何红蓼，李冰，韩丽荣，等.封闭压力酸溶-ICP-MS法分析地质样品中47个元素的评价［J］.分析实验室，2002，21（5）：8-12.
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