img

Wechat

Adv. Search

Gold Science and Technology ›› 2017, Vol. 25 ›› Issue (6): 127-132.doi: 10.11872/j.issn.1005-2518.2017.06.127

Previous Articles    

Research and Application of Resource Utilization of Primary Lead Smelting Slag

WANG Fulin 1,2,MIN Chendi 1   

  1. 1.School of Nuclear Resources Engineering,University of South China,Hengyang   421001,Hunan,China;
    2.Henan Key Laboratory for Green and Efficient Mining & Comprehensive Utilization of Mineral Resources,Henan Polytechnic University,Jiaozuo   454000,Henan,China
  • Received:2017-04-30 Revised:2017-06-23 Online:2017-12-30 Published:2018-05-18

Abstract:

The resource utilization of primary lead smelting slag is an effective method to solve the problem of the land occupation and destruction of the ecological environment due to the pile of primary lead smelting slag in the open air.This paper firstly introduced the origin and physical-chemical properties of primary lead smelting slag,then,it summarized the research status and application of the resource utilization of lead smelting slag at home and abroad and analyzed the difficulties and shortcomings of the utilization of lead smelting slag from the aspects of recycling elements in lead smelting slag,preparing building materials and cementitious materials for mine filling. Domestic and foreign studies show that the lead smelting slag has less ways of utilization compare to other types of slag and the research on secondary pollution after its utilization is not deep enough.Therefore,improving the smelting process to increase the recovery rate of valuable elements and widening utilization ways and forming proven techniques are prerequisites for large-scale resource utilization of lead smelting slag,meanwhile,it is necessary to carry out researches on the immobilization of harmful elements to confirm that the harmful elements in lead smelting slag can be prevented and controlled,so that the foundation can be laid for the resource utilization and safety and environmental disposal of lead smelting slag.

Key words:  lead smelting slag, resource utilization, secondary resources utilization, smelting process, secondary pollution, safety and environmental protection

CLC Number: 

  • X758
[1] China Industry Information Network.The overall development scale,development prospect and general development plan of China lead and zinc smelting industry in 2016[EB/OL].[2017-02-20].http://www.chyxx.com/industry/201608/ 435729.html. [中国产业信息网.2016年中国铅锌冶炼行业总体发展规模、发展前景及总发展规划解析[EB/OL].[2017-02-20].
http://www.chyxx.com/ industry/201608/435729.html.]
[2] Deng Xinhui,Chai Liyuan,Yang Zhihui,et al.Study of the characteristics of heavy metal pollution at Pb/Zn smelting slag site[J].Ecology and Environment Sciences,2015,24(9):1534-1539.[邓新辉,柴立元,杨志辉,等.铅锌冶炼废渣堆场土壤重金属污染特征研究[J].生态环境学报,2015, 24(9):1534-1539.]
[3] Ma Zhanwei,Wu Yonggui,Fu Tianling,et al.Distribution characteristics of heavy metals of different particle sizes in lead-zinc slag[J].Environmental Science & Technology,2015,38(4):149-154.[麻占威,吴永贵,付天岭,等.不同粒径铅锌冶炼废渣中重金属分布特征[J].环境科学与技术,2015,38(4):149-154.]
[4] Lin Xingjie.Status of heavy metal pollution in lead smelting industry and its countermeasures[J].Nonferrous Metals Engineering,2011,1(4):23-27.[林星杰.铅冶炼行业重金属污染现状及防治对策[J].有色金属工程,2011,1(4):23-27.]
[5] Li Kaimao,Cui Yaru,Wang Shangjie,et al.Status of lead pyrometallurgy and comprehensive utilization of its waste slag[J].China Nonferrous Metallurgy,2012,41(2):70-73.[李凯茂,崔雅茹,王尚杰,等.铅火法冶炼及其废渣综合利用现状[J].中国有色冶金,2012,41(2):70-73.]
[6] Xie Yuan,Fu Yi,Huang Peisheng,et al.Experiment research on consolidated fill of slag from lead refinery[J].Conservation and Utilization of Mineral Resources,2001(4):47-50.[谢源,付毅,黄沛生,等.炼铅炉渣胶结充填的试验研究[J].矿产保护与利用,2001(4):47-50.]
[7] Qin Wenqing,Zheng Yongxing,Liu Wei,et al.Mineralogical characterization of blast furnace slag quenched by water[J].The Chinese Journal of Nonferrous Metals,2014,24(1):262-268.[覃文庆,郑永兴,刘维,等.鼓风炉水淬铅冶渣的矿物特征[J].中国有色金属学报,2014,24(1):262-268.]
[8] Li Bing,Yang Shijiao,Wang Hongwu,et al.Experimental research on producing cementing material using smelter's lead refinery slag[J].Bulletin of the Chinese Ceramic So- ciety,2014,33(3):583-588.[李兵,杨仕教,王洪武,等.某冶炼厂炼铅炉渣制备胶凝材料的试验研究[J].硅酸盐通报,2014,33(3):583-588.]
[9] Lead and Zinc Metallurgical Editorial Board.Metallurgy of Lead and Zinc[M].Beijing:Science Press,2003:17-20.[铅锌冶金学编委会.铅锌冶金学[M].北京:科学出版社,2003:17-20.]
[10] Li Zhengshan,Jin Peng,Xu Defang.Retrieve lead from bearing-sulphur lead residue by chloride leaching[J]. Journal of Chengdu University of Science and Technology,1994(5):58-64.[李正山,金鹏,徐德芳.氯盐法从含硫铅渣中回收铅[J].成都科技大学学报,1994(5):58-64.]
[11] Yang Huifen,Li Caihong,Wang Chuanlong,et al.Antimony and copper recovery from iron tailings generated from lead slag using oxidizing acid leaching-tartaric acid comple- xation[J].Metal Mine,2015,44(9):175-180.[杨慧芬,李彩红,王传龙,等.氧化酸浸—酒石酸络合法从铅渣选铁尾矿中回收锑铜[J].金属矿山,2015,44(9):175-180.]
[12] Zhang Fusheng,Li Shumei,Cong Zifan.Regeneration of gypsum and hydrochloric acid by the slag of lead smelting[J].Non-ferrous Mining and Metallurgy,2011,27(3):30-32.[张福生,李淑梅,丛自范.用炼铅炉渣制备石膏及再生盐酸的研究[J].有色矿冶,2011,27(3):30-32.]
[13] Sun Hongyan,Kong Xin,Sen Wei,et al.Leaching of iron from water-quenched slag in lead smelting using surfuric acid[J].Hydrometallurgy of China,2015,34(3):222-224.[孙红燕,孔馨,森维,等.用硫酸从铅冶炼水淬渣中浸出铁的试验研究[J].湿法冶金,2015,34(3):222-224.]
[14] Zeng Maohua,Xi Changsheng,Peng Cuihong,et al.Study on floatating lead from waste residue of lead[J].Nonferrous Metals(Mineral Processing Section),2004(1):12-15.[曾懋华,奚长生,彭翠红,等.浮选含铅废渣富集铅的研究[J].有色金属(选矿部分),2004(1):12-15.]
[15] Zheng Y X,Liu W,Qin W Q,et al.Improvement for sulphidation roasting and its application to treat lead smelter slag and zinc recovery[J].Canadian Metallurgical Quarterly,2015,54(1):92-100.
[16] Wang C L,Yang H F,Jiang B P,et al.Recovery of iron from lead slag with coal-based direct reduction followed by magnetic separation[J].Advanced Materials Research,2014, 878:254-263.
[17] Albitar M,Ali M S M,Visintin P,et al.Effect of granulated lead smelter slag on strength of fly ash-based geopolymer concrete[J].Construction & Building Materials,2015,83:128-135.
[18] Alwaeli M.Application of granulated lead-zinc slag in concrete as an opportunity to save natural resources[J].Radiation Physics and Chemistry,2013,83(1):54-60.
[19] Saikia N,Cornelis G,Mertens G,et al.Assessment of Pb-slag,MSWI bottom ash and boiler and fly ash for using as a fine aggregate in cement mortar[J].Journal of Hazardous Materials,2008,154(1/2/3):766-777.
[20] Atzeni C,Massidda L,Sanna U.Use of granulated slag from lead and zinc processing in concrete technology[J].Cement and Concrete Research,1996,26(9):1381-1388.
[21] De Angelis G,Medici F.Reuse of slags containing lead and zinc as aggregate in a portland cement matrix[J].Journal of Solid Waste Technology and Management,2012,38(2):117-123.
[22] Saikia N,Cornelis G,Cizer O,et al.Use of Pb blast furnace slag as a partial substitute for fine aggregate in cement mortar[J].Journal of Material Cycles and Waste Management,2012,14(2):102-112.
[23] Buzatu T,Talpos E,Petrescu M I,et al.Utilization of granulated lead slag as a structural material in roads constructions[J].Journal of Material Cycles and Waste Management,2015,17(4):707-717.
[24] Ogundiran M B,Nugteren H W,Witkamp G J.Immobilisation of lead smelting slag within spent aluminate-fly ash based geopolymers[J].Journal of Hazardous Materials,2012, 248-249(1):29-36.
[25] Onisei S,Pontikes Y,Van G T,et al.Synthesis of inorganic polymers using fly ash and primary lead slag[J].Journal of Hazardous Materials,2012,205-206(3):101-110.
[26] Zhang D,Shi S L,Wang C B,et al.Preparation of cementitious material using smelting slag and tailings and the solidification and leaching of Pb2+[J].Advances in Materials Science & Engineering,2015(1):1-7.
[27] Wang Hongwu,Wu Aixiang,Jiang Zhiming.Influence of iron oxides on the grinding efficiency and the cementitious activity of water-granulated lead slag[J].Journal of Hunan University of Science & Technology(Natural Science Edition),2010,25(1):106-110.[王洪武,吴爱祥,蒋志明.铁氧化物对炼铅水淬炉渣粉磨性能及胶凝活性的影响[J].湖南科技大学学报(自然科学版),2010,25(1):106-110.]
[28] Benkendorff P N.Potential of lead/zinc slag for use in cemented mine backfill[J]. Mineral Processing & Extractive Metallurgy Imm Transactions,2006,115(3):171-173.
[29] Fu Yi,Xu Xiaohe,Ren Fengyu.Experimental study on cemented backfilling materials using large amount of nonferrous smelting slag[J].Nonferrous Metals(Mining),2001(2):13-14.[付毅,徐小荷,任凤玉.大用量有色炉渣胶结充填料试验研究[J].有色金属(矿山部分),2001(2):13-14.]
[30] Yang Xinhua,Yang Shijiao,Wang Hongwu,et al.Low activity of lead smelting slag cementitious materials used in all tailings paste filling[J].Journal of University of South China(Science and Technology),2013,27(4):28-31.[杨新华,杨仕教,王洪武,等.低活性炼铅炉渣胶凝材料应用于全尾砂膏体充填[J].南华大学学报(自然科学版),2013,27(4):28-31.]
 
 
[1] Tingting ZHANG, Shiwei ZHI, Lijie GUO, Zhenlin WU, Junnan HAN. Research Progress of Resource Utilization of Copper-Nickel Smelting Slag [J]. Gold Science and Technology, 2020, 28(5): 637-645.
[2] Xiaoming LIU,Lei DENG,Liguan WANG,Shunhua DENG,Xinfeng YANG,You WAN,Yanjun HE. Intelligent Mine Master Plan for Underground Metal Mine [J]. Gold Science and Technology, 2020, 28(2): 309-316.
[3] Weixiao ZHANG,Juansha LV,Jiwen ZHANG,Bo SUN. Experimental Study on Treatment of Chloride Ion in Gold Smelting Acid Was-tewater by Cuprous Oxide [J]. Gold Science and Technology, 2018, 26(5): 677-681.
[4] DAI Weiming,LEI Lu,FAN Qingfeng,WANG Yao. A Review of Research and Development Progress on the Smelting Process of Jamesonite [J]. Gold Science and Technology, 2015, 23(2): 98-102.
[5] CHEN Fangfang,ZHANG Yifei,XUE Guang. Disposal to Pollution and Resource Utilization to Waste for Gold Smelting [J]. J4, 2011, 19(2): 67-73.
[6] TIAN Hong-Wei, FU Cai-Yun, ZHANG Bao-Ren. Resource Evaluation of Explosion Breccia-type Gold Deposit in Qiyugou Area [J]. J4, 2010, 18(1): 6-10.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!