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  • ISSN 1005-2518 
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Mining Technology and Mine Management

Effect of Silver Content on Galena Flotation and Research Progress on Its Mechanism

  • Fangyin NIU ,
  • Jianping JIN ,
  • Guobin WANG ,
  • Haijun WANG ,
  • Zhuoyue LAN ,
  • Jun CHEN ,
  • Ruikang WANG ,
  • Yaru WEI ,
  • Qingping ZHAO ,
  • Di YANG ,
  • Boqi LI
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  • 1.Faculty of Land Resource Engineering,Kunming University of Science and Technology,Kunming 650093,Yunnan,China
    2.Yunnan Province Engineering Research Center for Reutilization of Metal Tailings Resources,Kunming 650093,Yunnan,China

Received date: 2021-01-11

  Revised date: 2021-07-15

  Online published: 2021-12-17

Abstract

The resources of silver-bearing galena in China are large,but the comprehensive recovery of silver is lower. Mostly mining enterprises and scientific research institutes have conducted studies tending to optimization of technological process and reagent regulation. Although they have made a great deal of achievements,they could not dissolve completely the radical issues that the recovery of silver is low. Meanwhile,the effect of silver content on flotation performance of galena is less explored,which leads to be difficult for the concentrator to significantly improve silver recovery index,resulting in incomplete of resources utiliazation and resources waste.For this reason,this paper summarized the work done by predecessors in detail,such as the resource status of silver-bearing galena,the current flotation process of silver-bearing galena and the reagent system. At the same time,the effects of silver content on the flotation behavior of galena were summarized,such as the increase of the surface area of synthetic silver-bearing galena,the change of Zeta potential in the slurry during flotation process,the different adsorption amount of collector on the surface of galena,and the transformation of electrochemical characteristic peak,etc.. The mechanism of the effect of the silver content on the flotation behavior of galena were analyzed in detail from experimental to simulation,macroscopic to microscopic aspects,respectively. At the last,in view of the shortcomings of the current resource characteristics,technological process,reagent system and research mechanism,some reasonable suggestions are also put forward for the development of silver-bearing lead-zinc ore resources,such as exploring the technical scheme or technological process with high efficiency and low cost,developing unifying reagent of cost,efficiency,environmental protection,non-toxic and harmless and so on.

Cite this article

Fangyin NIU , Jianping JIN , Guobin WANG , Haijun WANG , Zhuoyue LAN , Jun CHEN , Ruikang WANG , Yaru WEI , Qingping ZHAO , Di YANG , Boqi LI . Effect of Silver Content on Galena Flotation and Research Progress on Its Mechanism[J]. Gold Science and Technology, 2021 , 29(5) : 749 -760 . DOI: 10.11872/j.issn.1005-2518.2021.05.015

References

null Ao Shunfu,Wang Chunguang,Hu Hongxi,al et,2019. Processing experimental study on a low-grade lead-zinc ore containing silver[J]. Nonferrous Metals(Mineral Processing Section),(4):32-39.
null Barkhordari H R,Jorjani E,Eslami A,et al. 2009. Occurrence mechanism of silicate and aluminosilicate minerals in Sarcheshmeh copper flotation concentrate[J]. International Journal of Minerals,Metallurgy and Materials,16(5):494-499.
null Cao Jincheng,Cao Fei,Lü Liang,al et,2012. Study on mineral processing of a Pb-Zn-Ag polymetallic ore in Shandong province[J]. Industrial Minerals & Processing,41(1):20-21,30.
null Chen J H,Ke B L,Lan L H,al et,2015a. Influence of Ag,Sb,Bi and Zn impurities on electrochemical and flotation behavior of galena[J]. Minerals Engineering,(72):10-16.
null Chen J H,Ke B L,Lan L H,al et,2015b. DFT and experimental studies of oxygen adsorption on galena surface bearing Ag,Mn,Bi and Cu impurities[J].Minerals Engineering,(71):170-179.
null Chen J,Wang L,Chen Y,al et,2011. A DFT study of the effect of natural impurities on the electronic structure of galena[J]. International Journal of Mineral Processing,98(3/4):132-136.
null Chen Shenghu,2012. The Research of Beneficiation Process and Mechanism for a Lead-Zinc Ore in Guangdong[D]. Ganzhou:Jiangxi University of Science and Technology.
null Cheng Kai,2016.The Efficient and Environment-friendly Age-nts HQ77 and D82:Characterization,Mechanism,and Practical Application in Flotation of Lead-Zinc Separation[D]. Nanning:Guangxi University.
null Du Xianyan,2014. Mineral Processing Technology and Mechanism Studies on Lead-Zinc-Silver Polymetallic Sulphide Ore[D]. Ganzhou:Jiangxi University of Science and Te-chnology.
null Feng Qiming,Chen Jianhua,2014. Electrochemistry of Sulfide Mineral Flotation[M]. Changsha:Central South University of Technology Press.
null Fu Dan,2010. The Study of Flotation and Surface Adsorption Mechanism of Copper-Lead-Zinc Sulphide Ore[D]. Ganzhou:Jiangxi University of Science and Technology.
null Hansford G S,Vargas T,2001. Chemical and electrochemical basis of bioleaching processes[J].Hydrometallurgy,59(2/3):135-145.
null Huang Heping,2018. Study on the Flotation Characteristics of Different Particle Size of Lead-Zinc Sulfide Ore[D]. Ganzhou:Jiangxi University of Science and Technology.
null Ji Jun,2011. Research on phased flotation process of carbon-bearing lead-zinc ore with fine grain size[J].Nonferrous Me-tals(Mineral Processing Section),(3):8-11.
null Jiang Sufang,2011. Study on Pb-Zn-Ag of multi-metalliferous ore flotation technology in Tibet[J].Hunan Nonferrous Me-tals,27(2):10-14,48.
null Lan L H,Chen J H,Li Y Q,al et,2016. Microthermokinetic study of xanthate adsorption on impurity-doped galena[J]. Transactions of Nonferrous Metals Society of China,26(1):272-281.
null Lan Lihong,2012. The Effect of Lattice Defect of Galena on the Surface Property,Molecular Absorption of Flotation Reagents and Electrochemical Behavior[D].Nanning:Guangxi University.
null Lan Zhiqiang,2017. Study on Flotation Behavior and Mechanism of Silver-bearing Galena[D].Kunming:Kunming Uni-versity of Science and Technology.
null Lee K,Archibald D,McLean J,2009. Reuter flotation of mixed copper oxide and sulfide minerals with xanthate and hydroxamate collectors[J].Minerals Engineering,22(4):395-401.
null Li Weizhong,2007. Research on Flotation Separation of Complex Lead-Zinc-Sliver Sulfide Ore and Its Practice[D]. Changsha:Central South University.
null Li Yanling,Li Ronggai,Bai Limei,2020. Study on comprehensive recovery process of complex multi-metals Cu-Pb-Zn-Au-Ag Ore in Henan province[J]. Metal Mine,(2):82-87.
null Liu Jiaxiang,Wang Guanpu,Zhang Zhiyuan,1995. On the separation technology of lead-zinc sulfide combined middling[J]. Journal of Xi’an University of Architecture & Technology(Natural Science Edition),(4):457-460.
null Luo Xianping,Zhou Hepeng,Zhou Yue,al et,2011. New technique to improve dressing indexes of associated silver in complex lead-zinc ore[J]. Mining and Metallurgical Engineering,31(3):35-39.
null Mao Yilin,Chen Xiaoqing,Yang Jinzhong,al et,2011. Experimental research on mineral processing technology for separating a complex and refractory oxide lead-zinc ore[J]. Multipurpose Utilization of Mineral Resources,(1):6-10.
null Qin Wei,2013.Design Synthesis and Flotation Mechanism Study on Flotation Reagents for Silver Containing Lead-zinc Ore[D]. Beijing:China University of Mining & Technology,Beijing.
null Sand W,Gehrke T,Jozsa P G,al et,2001. Biochemistry of bacterial leaching—direct vs. indirect bioleaching[J]. Hydrometallurgy,59(2/3):159-175.
null Song Yan,2020. Study on the mineral processing technology of a complicated refractory lead,zinc and silver polymetallic ore[J]. China Metal Bulletin,(4):20-21.
null Tan Xin,He Fayu,Wu Weiguo,al et,2010. Mineral processing technology on sandstone type low grade lead-zinc oxide ore[J]. Nonferrous Metals Engineering,62(3):115-122.
null Tian Jiangtao,2018. Mineral Processing Experiment Study on a Skarn Pb-Zn Ore from Hebei Province[D].Tangshan:North China University of Science and Technology.
null Tong Xiong,1996. Theory and Practice of Microbiological Leaching[M]. Beijing:Metallurgical Press.
null Wang Chengxing,Ye Fuxing,Tong Xiong,al et,2013. Comprehensive recovery of associated silver from some silver-rich lead-zinc sulfide ore in Yunnan[J].Mining and Metallurgical Engineering,33(4):67-69,73.
null Wang Hu,2015. Mineral Processing Technology from Nanjing Lead-Zinc-Silver Ore and Studies on Flotation Kinetics[D]. Ganzhou:Jiangxi University of Science and Technology.
null Wang Lei,2010. The First Principle Study on the Effect of Lattice Defects on Electronic Structure and Flotation Behavior of Galena[D].Nanning:Guangxi University.
null Wang Qiang,2005. Experimental Research of Strengthen Silver Reclaim in Galena and Sphalerite[D]. Shenyang:Northeastern University.
null Wasserstein B,1951. Precision lattice measurements of galena[J]. American Mineralogist,36(1/2):102-115.
null Wen Kai,Chen Jianhua,2019. Experimental study on flotation of copper,lead and zinc polymetallic sulfide ore containing silver[J]. Multipurpose Utilization of Mineral Resources,(6):28-32.
null Woods R,2000.Recent advances in electrochemistry of sulfide mineral flotation[J]. Transactions of Nonferrous Metals Society of China,10(Supp.1):26-29.
null Wu Chuizhi,2012. Research on Flotation Behavior and Mechanism of Artificial Magnetite and Natural Magnetite[D]. Nanning:Guangxi University.
null Wu Rongqing,2008. China has made new progress in prospecting and exploitation of lead-zinc mineral resources[J]. China Metal Bulletin,(25):28-31.
null Xi Shen,2012. Analysis of present situation of silver mineral resources in China and Abroad[J]. World Nonferrous Metals,(6):60-63.
null Xiao Jun,Chen Daixiong,Yang Jianwen,2014. Research on beneficiation technology for a polymetallic sulphide ore containing high silver-copper-lead-zinc in Henan[J]. Multipurpose Utilization of Mineral Resources,(4):30-35.
null Xiao Tianxiang,2015. Experimental study on comprehensive recycling of a lead-zinc and silver polymetallic mineral[J]. Gansu Metallurgy,37(5):11-15,19.
null Zeng Xiaoqin,2009. The First Principle Study on the Effect of Lattice Defects on the Electronic Structure of Sphalerite[D]. Nanning:Guangxi University.
null Zhang Changqing,Rui Zongyao,Chen Yuchuan,al et,2013. The main successive strategic bases of resources for Pb-Zn deposits in China[J]. Geology in China,40(1):248-272.
null Zhang Yingxin,Zhang Chengqiang,Tian Min,2012. Experimental research on flotation technology for a low-grade lead-zinc-silver mineral separation[J]. Multipurpose Utilization of Mineral Resources,(6):28-32,36.
null Zhou Hepeng,2011. Study on Synthesis Recovery Technology and Mechanism of Associated Silver from Huili Zinc Ore in Sichuan Province[D]. Ganzhou:Jiangxi University of Science and Technology.
null Zhou Hongbo,Pang Yunjuan,2010. Experimental study on mineral processing of a lead zinc sulfide minerals[J]. Modern Mining,26(7):37-39.
null Zhou Jing,2010. Higher efficiency and non-toxic mineral separation technology of complex lead-zinc-sulphur[J].Nonferrous Metals(Mineral Processing Section),(4):43-48.
null Zhou Yuan,2002. The Dressing of Gold and Silver Ore[M]. Ganzhou:Jiangxi University of Science and Technology Press.
null Zhu Yimin,2010. The synthesis of the Ammonium Di-iso-butyl Dithiophosphate and its flotation effect[J]. Metal Mine,(9):68-70.
null 敖顺福,王春光,胡红喜,等,2019. 某含银低品位铅锌矿石选矿试验研究[J].有色金属(选矿部分),(4):32-39.
null 曹进成,曹飞,吕良,等,2012. 山东某铅锌银多金属矿选矿试验研究[J].化工矿物与加工,41(1):20-21,30.
null 陈胜虎,2012. 广东某铅锌矿选矿工艺及机理研究[D]. 赣州:江西理工大学.
null 程恺,2016. 铅锌分离浮选高效环保新药剂HQ77和D82性能、作用机理和实际应用研究[D].南宁:广西大学.
null 杜显彦,2014. 铅锌银多金属硫化矿选矿工艺及机理研究[D]. 赣州:江西理工大学.
null 冯其明,陈建华,2014. 硫化矿浮选电化学[M].长沙:中南大学出版社.
null 付丹,2010. 铜铅锌多金属硫化矿浮选行为与表面吸附机理研究[D]. 赣州:江西理工大学.
null 黄和平,2018. 不同粒级铅锌硫化矿浮选特性研究[D].赣州:江西理工大学.
null 纪军,2011. 微细粒含碳铅锌矿分步浮选工艺研究[J].有色金属(选矿部分),(3):8-11.
null 蒋素芳,2011.西藏某难选铅锌银硫多金属矿选矿工艺研究[J].湖南有色金属,27(2):10-14,48.
null 兰志强,2017. 含银方铅矿的浮选行为及机理研究[D].昆明:昆明理工大学.
null 蓝丽红,2012. 晶格缺陷对方铅矿表面性质、药剂分子吸附及电化学行为影响的研究[D].南宁:广西大学.
null 黎维中,2007. 难处理铅锌银硫化矿物资源综合回收的研究与实践[D].长沙:中南大学.
null 李彦令,李荣改,白丽梅,2020. 河南某复杂铜铅锌金银多金属矿综合回收工艺研究[J].金属矿山,(2):82-87.
null 刘家祥,王冠甫,张治元,1995. 硫化铅锌中矿分离工艺的研究[J].西安建筑科技大学学报,(4):457-460.
null 罗仙平,周贺鹏,周跃,等,2011. 提高某复杂铅锌矿伴生银选矿指标新工艺研究[J].矿冶工程,31(3):35-39.
null 毛益林,陈晓青,杨进忠,等,2011. 某复杂难选氧化铅锌矿选矿试验研究[J].矿产综合利用,(1):6-10.
null 秦伟,2013. 伴生银铅锌矿浮选药剂的设计、合成与浮选机理研究[D].北京:中国矿业大学(北京).
null 宋龑,2020. 某复杂难选铅锌银多金属矿选矿工艺研究[J].中国金属通报,(4):20-21.
null 谭欣,何发钰,吴卫国,等,2010. 某砂岩型低品位氧化铅锌矿选矿工艺[J].有色金属工程,62(3):115-122.
null 田江涛,2018. 河北省某矽卡型铅锌矿选矿试验研究[D].唐山:华北理工大学.
null 童雄,1996. 微生物浸矿的理论与实践[M].北京:冶金出版社.
null 王成行,叶富兴,童雄,等,2013. 云南某富银硫化铅锌矿中伴生银的综合回收研究[J].矿冶工程,33(4):67-69,73.
null 王虎,2015. 南京栖霞山高硫低铅锌银矿高效回收工艺及浮选动力学研究[D].赣州:江西理工大学.
null 王檑,2010. 晶格缺陷对方铅矿电子结构及浮选行为影响的第一性原理研究[D].南宁:广西大学.
null 王强,2005. 强化铅锌矿中伴生银回收的试验研究[D].沈阳:东北大学.
null 温凯,陈建华,2019. 某含银复杂铜铅锌多金属硫化矿浮选试验[J].矿产综合利用,(6):28-32.
null 吴荣庆,2008. 我国铅锌矿产资源勘查开发取得新进展[J].中国金属通报,(25):28-31.
null 伍垂志,2012. 人工磁铁矿和天然磁铁矿浮选行为及其机理研究[D].南宁:广西大学.
null 奚甡,2012.中外银矿资源现状分析[J].世界有色金属,(6):60-63.
null 肖骏,陈代雄,杨建文,2014. 河南某高含银铜铅锌多金属硫化矿选矿工艺研究[J].矿产综合利用,(4):30-35.
null 肖天祥,2015. 某铅锌金银多金属矿综合回收选矿试验研究[J].甘肃冶金,37(5):11-15,19.
null 曾小钦,2009. 晶格缺陷对闪锌矿电子结构影响的第一性原理研究[D].南宁:广西大学.
null 张长青,芮宗瑶,陈毓川,等,2013. 中国铅锌矿资源潜力和主要战略接续区[J].中国地质,40(1):248-272.
null 张颖新,张成强,田敏,2012. 豫西低品位铅锌银多金属矿浮选试验研究[J].矿产综合利用,(6):28-32,36.
null 周贺鹏,2011. 四川会理锌矿伴生银综合回收工艺及机理研究[D]. 赣州:江西理工大学.
null 周宏波,庞运娟,2010. 某铅锌硫化矿选矿试验研究[J].现代矿业,26(7):37-39.
null 周菁,2010. 难选铅锌硫矿无毒高效选矿药剂试验研究[J].有色金属(选矿部分),(4):43-48.
null 周源,2002. 金银矿石的选矿[M].赣州:江西理工大学出版社.
null 朱一民,2010. 异丁基铵黑药的合成及浮选效果[J].金属矿山,(9):68-70.
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